Princeton University

Scientists copy nature to split water into hydrogen and oxygen

An international team of researchers has used chemicals found in plants to replicate a key process in photosynthesis, paving the way to a new approach that uses sunlight to split water into hydrogen and oxygen.

Washington, August 18 : An international team of researchers has used chemicals found in plants to replicate a key process in photosynthesis, paving the way to a new approach that uses sunlight to split water into hydrogen and oxygen.

The breakthrough, led by Monash University in Australia, could revolutionize the renewable energy industry by making hydrogen - touted as the clean, green fuel of the future - cheaper and easier to produce on a commercial scale.

It came about after Professor Leone Spiccia, Robin Brimblecombe and Dr Annette Koo from Monash University teamed with Dr Gerhard Swiegers at the CSIRO and Professor Charles Dismukes at Princeton University to develop a system comprising a coating that can be impregnated with a form of manganese, a chemical essential to sustaining photosynthesis in plant life.

"We have copied nature, taking the elements and mechanisms found in plant life that have evolved over 3 billion years and recreated one of those processes in the laboratory," Professor Spiccia said.

According to Professor Spiccia, a manganese cluster is central to a plant's ability to use water, carbon dioxide and sunlight to make carbohydrates and oxygen.

Professor Charles Dismukes developed man-made mimics of this cluster some time ago, and the research team took it a step further, harnessing the ability of these molecules to convert water into its component elements, oxygen and hydrogen.

"The breakthrough came when we coated a proton conductor, called Nafion, onto an anode to form a polymer membrane just a few micrometres thick, which acts as a host for the manganese clusters," said Spiccia.

"Normally insoluble in water, when we bound the catalyst within the pores of the Nafion membrane, it was stabilised against decomposition and, importantly, water could reach the catalyst where it was oxidized on exposure to light," he added.

This process of "oxidizing" water generates protons and electrons, which can be converted into hydrogen gas instead of carbohydrates as in plants.

"Whilst man has been able to split water into hydrogen and oxygen for years, we have been able to do the same thing for the first time using just sunlight, an electrical potential of 1.2 volts and the very chemical that nature has selected for this purpose," Spiccia said.

Testing revealed the catalyst assembly was still active after three days of continuous use, producing oxygen and hydrogen gas in the presence of water, an electrical potential and visible light.

According to Spiccia, the efficiency of the system needed to be improved, but this breakthrough had huge potential.

"We need to continue to learn from nature so that we can better master this process," he said.

"The production of hydrogen using nothing but water and sunlight offers the possibility of an abundant, renewable, green source of energy for the future for communities across the world," he added.

ANI