Luminescent polymers could pave way for brighter laptop, cellphone LEDs, longer battery life

A team of US and Japanese scientists have developed a new and inexpensive means of forcing luminescent polymers to give off polarized light, which could lead to brighter source for LEDs in laptops, cellphones, and other consumer electronics devices of the future. This would also lead to less power consumption and a longer battery life, they said.

Washington, Sept 19 : A team of US and Japanese scientists have developed a new and inexpensive means of forcing luminescent polymers to give off polarized light, which could lead to brighter source for LEDs in laptops, cellphones, and other consumer electronics devices of the future. This would also lead to less power consumption and a longer battery life, they said.

The researchers have succeeded in taking semiconducting polymers - plastics consisting of long chains of atoms that work as semiconductors - and stretching them out in a silica (glass) host matrix so that they have new optical properties.

"If you have polymer chains that can wiggle like spaghetti, it's hard to make them all point in the same direction. What we do is take tiny, nanometer-sized holes in a piece of glass and force the polymer chains into the holes. The holes are so small that the spaghetti chains have no space to coil up. They have to lie straight, and all the chains end up pointing in the same direction," said Sarah Tolbert, University of California, Los Angeles professor of chemistry and California NanoSystems Institute member.

Prof. Tolbert said since the chains point in the same direction, they absorb polarized light and give off polarized light.

"Lining up the polymer chains also provides advantages for laser technology, because all the chains can participate in the lasing process, and they can make the light polarized without the need for any external optical elements," she said in her study.

Co-author Benjamin J. Schwartz, also a UCLA professor of chemistry and California NanoSystems Institute member, said, "our new materials exploit the fact that the polymer chains are all lined up to make them into lasers that function very differently from lasers made out of random polymers".

Prof. Schwartz said, the manner in which the polymer chains incorporate into the porous glass of the silica matrix helps to confine the light in the material, enhancing the lasing process by producing what is known as a "graded-index waveguide."

"In most lasers, confining the light is typically done with external mirrors. Our materials don't need mirrors to function as lasers, because the material that's lasing is also serving to confine the light," he said.

The researchers said, that in combination, the alignment of the polymer chains and the confinement of the light make it 20 times easier for the new materials to lase than if a randomly oriented polymer sample were used.

"Since the polymers can be dissolved easily in solvents, they are inexpensive to process. The glass host matrix with the aligned nanoscale pores is also inexpensive to produce. Usually polarized and cheap don't go together," Prof. Tolbert said.

She said the research has opened the possibility of additional applications for the new materials as a brighter polarized source for displays in products with LED-type displays, including cell phones, laptops and Palm Pilots.

"If you take an inexpensive light source with which you could excite the aligned polymer chains and get the chains to reemit, you potentially have a more efficient way to generate polarized light. This would allow displays to be brighter with less power consumption, and you could get longer battery life," she said.

The research appears in the online edition of the journal Nature Nanotechnology. Hirokatsu Miyata from Canon Nanocomposite Research, Japan, also took part in the study.

ANI